1-Naphthalene acetic acid

  • alpha-Naphthaleneacetic acid.
  • 2-(1-Naphthyl)acetic acid
  • ANA
  • Appl-Set
  • Celmone
  • Floramon
Formula
C12H10O2
Structure
Description
Odorless, off-white powder.
Uses
herbicide

Registry Numbers and Inventories.
CAS
86-87-3
EC (EINECS/ELINCS)
201-705-8
EC Class
harmful, irritant
R 22 36/37/38
S 26 36/37/39
RTECS
QJ0875000
RTECS class
Agricultural Chemical and Pesticide; Mutagen; Primary Irritant
Merck
12,6458
Beilstein/Gmelin
1308415
Beilstein Reference
4-09-00-02424
EPA OPP
56002
Swiss Giftliste 1
G-6356
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C12H10O2
Formula mass
186.21
Melting point, °C
129 - 131
Boiling point, °C
352
Vapor pressure, mmHg
Negligable.
Density
1.263 g/cm3
Solubility in water
0.38 g/L
pKa/pKb
4.30 (pKa)
Partition coefficient, pKow
2.59

Hazards and Protection.
Storage
Store in a cool, dry place. Keep container closed when not in use.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment.
Disposal code
4
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Oxidizing agents.
Decomposition
Irritating and toxic fumes and gases.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.

Health.
Poison_Class
4
Exposure effects
The toxicological properties of this substance have not been fully investigated.
   Ingestion
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
   Inhalation
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.
   Skin
Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
   Eyes
May cause severe eye irritation. May result in corneal injury.

First aid
 
   Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
4. Organic acids
HS Code
2916 39 00