1,3-Epoxypropane

  • cyclooxabutane
  • oxacyclobutane
  • Oxetan
  • Oxetane
  • alpha,gamma-Propane oxide
  • Trimethylene oxide
Formula
C3H6O
Structure
Description
Clear, colorless liquid with an agreeable aromatic odor.
Uses
Chemical int, eg, for epoxy resins & 3-substituted propanols.

Registry Numbers and Inventories.
CAS
503-30-0
EC (EINECS/ELINCS)
207-964-3
EC Index Number
603-058-00-0
EC Class
Highly flammable; Harmful
R 11 20/21/22
S 9 16 26 29
RTECS
RQ6825000
RTECS class
Tumorigen; Mutagen
UN (DOT)
1992
Merck
12,9846
Beilstein/Gmelin
102382
Beilstein Reference
5-17-01-00011
Canada DSL/NDSL
NDSL
US TSCA
Listed
New Zealand
Listed

Properties.
Formula
C3H6O
Formula mass
58.08
Melting point, °C
-97
Boiling point, °C
50
Vapor pressure, mmHg
320 (25 C)
Critical temperature
235
Critical pressure
52.31
Density
0.8975 g/cm3 (0 C)
Solubility in water
Very soluble
Refractive index
1.3895 (20 C)
Partition coefficient, pKow
-0.14
Heat of fusion
6.49 kJ/mol
Heat of vaporization
28.7 kJ/mol

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respirators
When working with this chemical, wear a NIOSH-approved full face chemical cartridge respirator equipped with the appropriate organic vapor cartridges. If that is not available, a half face respirator similarly equipped plus airtight goggles can be substituted. However, please note that half face respirators provide a substantially lower level of protection than do full face respirators.
Small spills/leaks
If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Disposal code
1
Stability
No data.
Incompatibilities
Reacts with Grignard reagents and organolithium compounds Incompatible with oxidizing agents and strong acids.

Fire.
Flash Point,°C
-32
Upper exp. limit, %
37
Lower exp. limit, %
2.8
Fire fighting
Fires involving this material should be controlled with a dry chemical carbon dioxide or Halon extinguisher.
Fire potential
This chemical is flammable.

Health.
Exposure effects
   Ingestion
See inhalation.
   Inhalation
Exposure to this compound may cause irritation.
   Skin
See inhalation.
   Eyes
See inhalation

First aid
 
   Ingestion
DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital.
   Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
   Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
   Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Transport.
UN number
1992
Response guide
HS Code
2932 99 50