2-Bromopropiophenone

  • 1-Benzoyl-1-bromoethane
  • a-Methylphenacyl bromide
  • 1-Bromoethyl phenyl ketone
  • 2-Bromo-1-phenyl-1-propanone
Formula
C6H5COCH(Br)CH3
Structure
Description
Clear yellow.

Registry Numbers and Inventories.
CAS
2114-00-3
EC (EINECS/ELINCS)
218-307-5
EC Class
irritant
R 36/37/38
S 26 36/37/39
RTECS
UG8400000
RTECS class
Other
UN (DOT)
2810
Beilstein/Gmelin
508550
Beilstein Reference
4-07-00-00684
Canada DSL/NDSL
NDSL
US TSCA
Listed
New Zealand
Listed

Properties.
Formula
C9H9BrO
Formula mass
213.08
Boiling point, °C
245
Density
1.439 g/cm3 (0 C)
Solubility in water
Insoluble
Refractive index
1.5717 (20 C)

Hazards and Protection.
Storage
Refrigerator (approx 4 C).
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Disposal code
2
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents - strong bases.

Fire.
Flash Point,°C
> 112
Fire fighting
Small Fires: Dry chemical, carbon dioxide or water spray. Large Fires: Dry chemical, carbon dioxide, alcohol-resistant foam or water spray.
Fire potential
Combustible material: may burn but does not ignite readily.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure effects
   Ingestion
Not available.
   Inhalation
Not available.
   Skin
Not available.
   Eyes
Lachrymator.

First aid
 
   Ingestion
Do NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice.
   Inhalation
Remove from exposure to fresh air immediately.
   Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Immediately flush with running water for at least 20 minutes.

Transport.
UN number
2810
Response guide
Hazard class
6.1
Packing Group
I; II; III
 
HS Code
2914 70 90