(-{2}-H6)Phenol

  • Phenol-d6
Formula
[2H]6C6O
Structure
Description
Colorless crystals.

Registry Numbers and Inventories.
CAS
13127-88-3
EC (EINECS/ELINCS)
236-063-8
EC Class
toxic, corrosive
R 24/25 34
S 26 28.1 36/37/39 45
UN (DOT)
1671
Beilstein/Gmelin
NA
New Zealand
Listed

Properties.
Formula
C6D6O
Formula mass
100.14
Melting point, °C
40.8
Boiling point, °C
180
Solubility in water
84 g/L (20 C)

Hazards and Protection.
Storage
Store in a tightly closed container. Corrosives area. Store protected from moisture. Store protected from light. Store in a cool, dry area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Store protected from light. Use only in a chemical fume hood. Discard contaminated shoes. Do not breathe dust.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Small spills/leaks
Avoid runoff into storm sewers and ditches which lead to waterways. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Disposal code
9
Stability
Stable under normal temperatures and pressures. May discolor on exposure to light. Hygroscopic: absorbs moisture or water from the air.
Incompatibilities
Moisture, direct light, strong oxidizing agents, strong bases, strong acids.
Decomposition
Carbon monoxide, carbon dioxide.

Fire.
Flash Point,°C
85
Autoignition, °C
595
Upper exp. limit, %
9.5
Lower exp. limit, %
1.3
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Do NOT get water inside containers.
Fire potential
Combustible material: may burn but does not ignite readily.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
3
 
Flammability
0
 
 
Reactivity
0
 

Health.
Exposure effects
Prolonged or repeated exposure may cause permanent eye damage. Effects may be delayed. Prolonged or repeated exposure may cause liver or kidney damage.
   Ingestion
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma. May cause cardiopulmonary system effects.
   Inhalation
Causes chemical burns to the respiratory tract. May cause effects similar to those described for ingestion. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. May cause systemic effects. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
   Skin
Causes skin burns. Substance is rapidly absorbed through the skin. May cause severe pain, swelling, tissue destruction, and possible shock. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
   Eyes
Causes eye burns. May cause chemical conjunctivitis and corneal damage.

First aid
 
   Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
   Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Transport.
UN number
1671
Response guide
Hazard class
6.1
Packing Group
II
 
HS Code
2845 90 10