2-Methyl-3-hexanone

  • Isopropyl propyl ketone
  • Propyl isopropyl ketone
Formula
C7H14O
Structure

Registry Numbers and Inventories.
CAS
7379-12-6
EC (EINECS/ELINCS)
230-940-9
16 29 33
RTECS
MP3900000
RTECS class
Primary Irritant
UN (DOT)
1224
Beilstein/Gmelin
1699041
Beilstein Reference
4-01-00-03328
Canada DSL/NDSL
DSL

Properties.
Formula
C7H14O
Formula mass
114.21
Boiling point, °C
131 - 132
Vapor pressure, mmHg
8.2 (25 C)
Critical temperature
320
Density
0.8428 g/mL (20 C)
Solubility in water
Slightly soluble
Refractive index
1.4080 (20 C)
Heat of vaporization
37.2 kJ/mol

Hazards and Protection.
Storage
Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place.
Protection
Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, Carbon dioxide.

Fire.
Flash Point,°C
24
Fire fighting
Extinguish using Carbon dioxide, dry chemical powder, or appropriate foam. Water spray. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Fire potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure effects
   Inhalation
May cause irritation or burns.
   Skin
See Inhalation.
   Eyes
See Inhalation.

First aid
 
   Ingestion
Seek medical assistance.
   Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
   Skin
Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with running water for at least 20 minutes
   Eyes
Flush with running water for at least 20 minutes.

Transport.
UN number
1224
Response guide
Hazard class
3
Packing Group
III