2-Propanone, hexafluoro, sesquihydrate

  • Acetone, hexafluoro, sesquihydrate
  • Hexafluoroacetone-sesquihydrate
  • Hexafluoro-2-propanone-sesquihydrate
Formula
2CF3COCF3 . 3H2O
Structure
Description
Clear colorless liquid.

Registry Numbers and Inventories.
CAS
13098-39-0
EC (EINECS/ELINCS)
211-676-3
EC Class
toxic, irritant
R 24/25 36/37/38
S 36/37 45
RTECS
UC2660000
RTECS class
Drug; Reproductive Effector; Primary Irritant
UN (DOT)
2552
Beilstein/Gmelin
NA
Swiss Giftliste 1
G-6898
Austrailia AICS
Listed
New Zealand
Listed

Properties.
Formula
2C3F6O.3H2O
Formula mass
386.09
Melting point, °C
11 - 20
Vapor pressure, mmHg
1520 (30 C)
Density
1.69 g/cm3
Solubility in water
Soluble

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Disposal code
2
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen fluoride.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use water spray, dry chemical, or carbon dioxide.
Fire potential
Non-Combustible
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Poison_Class
1
Exposure effects
   Ingestion
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause a narcotic effect with possible coma.
   Inhalation
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. Toxic if inhaled.
   Skin
May cause irritation with pain and stinging, especially if the skin is abraded. Toxic in contact with skin.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
   Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
UN number
2552
Response guide
Hazard class
6.1
Packing Group
II
 
HS Code
2914 70 90