3-Bromobiphenyl

  • m-Bromobiphenyl
  • 3-Xenyl bromide
  • 3-Bromo-1,1'-biphenyl
  • 1-Bromo-3-phenylbenzene
  • [1,1'-Biphenyl]-3-yl bromide
Formula
C12H9Br
Structure
Description
Clear yellow viscous liquid.

Registry Numbers and Inventories.
CAS
2113-57-7
EC (EINECS/ELINCS)
218-304-9
RTECS
DV1750000
RTECS class
Other
UN (DOT)
2315
Beilstein/Gmelin
2043191
Beilstein Reference
4-05-00-01818
Swiss Giftliste 1
G-5859
Canada DSL/NDSL
NDSL
US TSCA
Listed
Japan ENCS (MITI)
Listed

Properties.
Formula
C12H9Br
Formula mass
233.10
Melting point, °C
9
Boiling point, °C
299
Vapor pressure, mmHg
0.002 (25 C)
Density
1.41 g/cm3 (20 C)
Solubility in water
Insoluble
Refractive index
1.6411 (20 C)
Partition coefficient, pKow
4.72
Heat of vaporization
51.8 kJ/mol

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Stability
No data.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.

Fire.
Flash Point,°C
136
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Fire potential
This material is probably combustible.
Hazards
Containers may explode when heated.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Poison_Class
4
Exposure effects
The toxological properties of this substance have not been fully investigated.
   Ingestion
May cause irritation of the digestive tract. May be harmful if swallowed.
   Inhalation
Causes respiratory tract irritation. May be harmful if inhaled.
   Skin
Causes skin irritation. May be harmful if absorbed through the skin.
   Eyes
Causes eye irritation.

First aid
 
   Ingestion
Get medical aid. Wash mouth out with water.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
2315
Response guide
Hazard class
9
Packing Group
II