4-Bromo-1-(bromomethyl)-2-fluorobenzene

  • Benzene, 4-bromo-1-(bromomethyl)-2-fluoro-
Formula
C7H5Br2F
Structure
Description
White solid. Characteristic odor.

Registry Numbers and Inventories.
CAS
76283-09-5
EC (EINECS/ELINCS)
278-412-7
R 34 36
S 26 36/37/39 45
UN (DOT)
3261
Beilstein/Gmelin
4307676

Properties.
Formula
C7H5Br2F
Formula mass
267.92
Melting point, °C
30
Boiling point, °C
126 (19 torr)

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container. Corrosives area.
Handling
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.
Stability
Stable under normal shipping and handling conditions.
Incompatibilities
Oxidizing agents, strong bases.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen fluoride, hydrogen bromide.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide.

Health.
Exposure effects
   Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
   Inhalation
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
   Skin
Causes skin burns.
   Eyes
Causes eye burns. Lachrymator.

First aid
 
   Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
UN number
3261
Response guide