4-Nitroanisole

  • 1-Methoxy-4-nitrobenzene
Formula
C7H7NO3
Structure
Description
A light red or amber-colored liquid or crystals.
Uses
Used to make other chemicals.

Registry Numbers and Inventories.
CAS
100-17-4
EC (EINECS/ELINCS)
202-825-3
S 22 36/37
RTECS
BZ8800000
RTECS class
Drug; Mutagen
UN (DOT)
2730
Merck
12,6682
Beilstein/Gmelin
1865361
Beilstein Reference
4-06-00-01282
Canada DSL/NDSL
NDSL
US TSCA
Listed
Austrailia AICS
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C7H7NO3
Formula mass
153.15
Melting point, °C
9.4
Boiling point, °C
260
Density
1.2540 g/cm3 (20 C)
Solubility in water
0.47 g/L
Viscosity
0.901 cp (131 C)
Surface tension
40.9 g/s2 (61 C)
Refractive index
1.5070 (60 C)

Hazards and Protection.
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Do not get water inside containers.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide.

Fire.
Flash Point,°C
130
Autoignition, °C
458
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For large fires, use water spray, fog, or alcohol-resistant foam. For small fires, use dry chemical, carbon dioxide, halon, or water spray.
Fire potential
May burn but does not ignite readily.
Hazards
Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure limit(s)
OEL-RUSSIA:STEL 3 mg/m3
Exposure effects
   Ingestion
May cause irritation of the digestive tract. May be harmful if swallowed.
   Inhalation
Effects may be delayed. May cause respiratory tract irritation.
   Skin
May cause skin irritation. If absorbed, causes symptoms similar to those of ingestion. May cause skin burns. Effects may be delayed.
   Eyes
May cause eye irritation. May cause eye burns.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
2730
Response guide
Hazard class
6.1
Packing Group
III
 
Std. Transport #
4925145