9-Bromophenanthrene

  • 9-Phenanthryl bromide
Formula
C14H9Br
Structure
Description
Very slightly yellow solid.

Registry Numbers and Inventories.
CAS
573-17-1
EC (EINECS/ELINCS)
209-351-6
S 22 24/25
RTECS
SF7197000
RTECS class
Mutagen
Beilstein/Gmelin
1869927
Beilstein Reference
4-05-00-02303
New Zealand
Listed

Properties.
Formula
C14H9Br
Formula mass
257.14
Melting point, °C
62
Boiling point, °C
390
Vapor pressure, mmHg
6E-6 (25 C)
Density
1.4093 g/cm3 (101 C)
Solubility in water
Insoluble
Refractive index
1.6799 (100.7 C)
Partition coefficient, pKow
5.45
Heat of vaporization
61.4 kJ/mol

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Protection
Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.
Disposal code
3
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.

Fire.
Flash Point,°C
190
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Health.
Exposure effects
   Ingestion
The toxicological properties of this substance have not been fully investigated.
   Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
   Skin
May cause skin irritation.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
Get medical aid. Wash mouth out with water.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
HS Code
2903 69 90