Acetobromglucose

  • Acetobromoglucose
  • a-Bromoglucose tetraacetate
  • 1-Bromo-a-D-glucose tetraacetate
  • Tetra-O-acetyl-a-D-glucosyl bromide
  • 2,3,4,6-Tetra-o-acetyl-alpha-d-glucopyranosyl bromide
  • a-D-Glucopyranosyl bromide, tetraacetate
Formula
C14H19BrO9
Structure
Description
White solid. Trace ethereal odor.

Registry Numbers and Inventories.
CAS
572-09-8
EC (EINECS/ELINCS)
209-339-0
S 22 24/25
Merck
13,61
Beilstein/Gmelin
96669
Beilstein Reference
5-17-06-00368
Canada DSL/NDSL
DSL
New Zealand
Listed

Properties.
Formula
C14H19BrO9
Formula mass
411.21
Melting point, °C
85 - 88
Boiling point, °C
125 - 130 (0.0005 torr)
Solubility in water
Insoluble

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Deep freeze (below -20 C).
Handling
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.
Disposal code
3
Stability
May decompose on exposure to moist air or water.
Incompatibilities
Strong oxidizing agents
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

Health.
Exposure effects
   Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
   Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
   Skin
May cause skin irritation.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
HS Code
2932 99 95