Acetone azine

  • Dimethyl ketazine
  • Acetone (1-methylethylidene)hydrazone
  • Acetone ketazine
  • 2-Propanone, (1-methylethylidene)hydrazone
Formula
C6H12N2
Structure

Registry Numbers and Inventories.
CAS
627-70-3
EC (EINECS/ELINCS)
211-009-6
10 36/37/38
16 26 36/37/39
RTECS
UC3080550
RTECS class
Other
UN (DOT)
1993
Beilstein/Gmelin
956583
Beilstein Reference
4-01-00-03207
Canada DSL/NDSL
NDSL
US TSCA
Listed

Properties.
Formula
C6H12N2
Formula mass
112.20
Melting point, °C
-12.5
Boiling point, °C
127 - 130
Vapor pressure, mmHg
11 (25 C)
Density
0.8398 g/mL (20 C)
Solubility in water
Very soluble
Surface tension
26.02 g/s2 (25 C)
Refractive index
1.4504 (20 C)
pKa/pKb
4.84 (pKb)
Heat of vaporization
35.5 kJ/mol

Hazards and Protection.
Storage
Keep tightly closed. Keep away from heat, sparks, and open flame. Store in a cool dry place.
Protection
Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.
Incompatibilities
Strong oxidizing agents.
Decomposition
Carbon monoxide, Carbon dioxide, Nitrogen oxides.

Fire.
Flash Point,°C
31
Fire fighting
Extinguish using Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Fire potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure effects
Flammable. Irritant. Irritating to eyes, respiratory system and skin.
   Inhalation
Vapors may cause dizziness or suffocation. May cause irritation or burns.
   Skin
May cause irritation or burns.
   Eyes
See Skin.

First aid
 
   Ingestion
Seek medical assistance.
   Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
   Skin
Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with running water for at least 20 minutes
   Eyes
Flush with running water for at least 20 minutes.

Transport.
UN number
1993
Response guide
Hazard class
3