a-Bromotoluic acid

  • a-Bromo-p-toluic acid
  • p-Carboxybenzyl bromide
  • 4-Carboxybenzyl bromide
  • 4-(Bromomethyl)benzoic acid
  • p-(Bromomethyl)benzoic acid
Formula
4-(BrCH2)C6H4COOH
Structure
Description
White powder.

Registry Numbers and Inventories.
CAS
6232-88-8
EC (EINECS/ELINCS)
228-343-3
S 26 36/37/39 45
UN (DOT)
1759
Beilstein/Gmelin
1862870
Beilstein Reference
4-09-00-01745
Canada DSL/NDSL
NDSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed

Properties.
Formula
C8H7BrO2
Formula mass
215.05
Melting point, °C
223 - 226
Boiling point, °C
316
Solubility in water
Soluble
pKa/pKb
4.10 (pKa)
Partition coefficient, pKow
2.36

Hazards and Protection.
Storage
Store in a cool, dry place. Keep container closed when not in use. Corrosives area. Store protected from moisture.
Handling
Use only in a well ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Disposal code
4
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Oxidizing agents, bases, alcohols, amines, steel, moisture.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen bromide.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Contact with water forms corrosive vapors. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out.
Fire potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Hazards
Contact with metals may evolve flammable hydrogen gas.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
3
 
Flammability
0
 
 
Reactivity
0
 

Health.
Exposure effects
Effects may be delayed.
   Ingestion
Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause central nervous system effects. May cause cardiac abnormalities. May cause systemic effects.
   Inhalation
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause cardiac abnormalities. May cause systemic effects.
   Skin
Causes severe skin irritation and burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
   Eyes
Lachrymator. Causes eye irritation and burns. May cause chemical conjunctivitis and corneal damage.

First aid
 
   Ingestion
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
   Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
   Eyes
Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Transport.
UN number
1759
Response guide
Hazard class
8
Packing Group
I; II; III
 
HS Code
2916 39 00