Barium nitrate

  • Nitrobarite
Formula
Ba(NO3)2
Structure
Description
A white crystalline solid.
Uses
Manufacture barium oxide (bao2), pyrotechnics for green fire, green signal lights, in vacuum tube industry.

Registry Numbers and Inventories.
CAS
10022-31-8
EC (EINECS/ELINCS)
233-020-5
RTECS
CQ9625000
RTECS class
Human Data; Primary Irritant
UN (DOT)
1446
Merck
12,1012
Beilstein/Gmelin
20111 (G)
RCRA
D005
Swiss Giftliste 1
G-1824
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
BaN2O6
Formula mass
261.33
Melting point, °C
592
Decomposition point, °C
657 - 718
Odor Threshold Odor threshold Odorless
Density
3.23 g/cm3
Solubility in water
79 g/L (20 C)
Refractive index
1.5659 (25 C)
Dielectric constant
5.89 (18 C)
Thermal expansion
1.67E-5/K (10 C)
Heat of fusion
24.7 kJ/mol

Hazards and Protection.
Storage
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from reducing agents.
Handling
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Do not use combustible materials such as paper towels to clean up spill.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Reducing agents.
Decomposition
Nitrogen oxides, irritating and toxic fumes and gases, barium oxide.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Contact professional fire-fighters immediately. For small fires DO NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires, flood fire area with water from a distance.
Fire potential
Nonflammable.
Hazards
May explode from heat or contamination.
Combustion products
Yields toxic gaseous oxides of nitrogen when involved in fire.
Health
1
 
Flammability
0
 
 
Reactivity
0
 
 
Special
O

Health.
Exposure limit(s)
NIOSH REL*: TWA 0.5 mg/m3 OSHA PEL*: TWA 0.5 mg/m3 [*Note: PEL and REL apply to other soluble Ba cmpds (as Ba) except Barium sulfate.] IDLH 50 mg/m3 (as Ba)
Poison_Class
2
Exposure effects
May cause digestive tract and cardiac disturbances. May cause kidney damage.
   Ingestion
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause hemorrhaging of the digestive tract. May cause abdominal pain, irregular heartbeat, slow pulse rate, convulsions, muscular spasms, low blood potassium, and paralysis.
   Inhalation
Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death.
   Skin
May cause skin irritation.
   Eyes
Causes eye irritation.

First aid
 
   Ingestion
Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
1446
Response guide
Hazard class
5.1
Packing Group
II
 
USCG CHRIS Code
BNT
 
Std. Transport #
4918709