Butyric acid

  • Butanoic acid
  • n-Butyric acid
Formula
CH3CH2CH2COOH
Structure
Description
Colorless, oily liquid, unpleasant, penetrating, rancid, butter-like odor.
Uses
Chemical intermediate for cellulose derivatives in lacquers & plastics, for pharmaceuticals, emulsifiers and disinfectants, leather tanning agent for deliming & swelling hides, sweetening agent in gasolines.

Registry Numbers and Inventories.
CAS
107-92-6
EC (EINECS/ELINCS)
203-532-3
EC Index Number
607-135-00-X
EC Class
Corrosive
S 26 36 45
RTECS
ES5425000
RTECS class
Mutagen; Primary Irritant
UN (DOT)
2820
Merck
13,1593
Beilstein/Gmelin
906770
Beilstein Reference
4-02-00-00779
Swiss Giftliste 1
G-2169
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C4H8O2
Formula mass
88.11
Melting point, °C
-8 - -5
Boiling point, °C
163.5
Vapor pressure, mmHg
0.4 (25 C)
Vapor density (air=1)
3.04
Saturation Concentration
0.0566% at 20 C
Evaporization number
0.06 (butyl acetate=1)
Odor Threshold Odor threshold 0.001 mg/m3
Critical temperature
345
Critical pressure
38.98
Density
0.958 g/cm3 (20 C)
Solubility in water
Soluble
Viscosity
1.41 cp (25 C)
Surface tension
26.8 g/s2 @ 20 C
Refractive index
1.39775 (15 C)
Dipole moment
1.65 D
Dielectric constant
2.98 (10 C)
pKa/pKb
4.82 (pKa)
Partition coefficient, pKow
0.79
Heat of fusion
11.6 kJ/mol
Heat of vaporization
63.6 kJ/mol
Heat of combustion
-2180 kJ/mol

Hazards and Protection.
Storage
Keep away from heat, sparks, and flame. Keep away from heat and flame. Keep away from sources of ignition. Do not store in direct sunlight. Keep container closed when not in use. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.
B3 E
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Absorb spill with an alkaline material such as soda ash or lime. Carefully scoop up and place into appropriate disposal container. Provide ventilation.
Disposal code
4
Stability
Stable under normal shipping and handling conditions.
Incompatibilities
Oxidizing agents, ammonia, sulfuric acid, isocyanates, epichlorohydrin, aliphatic amines, caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide).
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Fire.
Flash Point,°C
69
Autoignition, °C
425
Upper exp. limit, %
12.3
Lower exp. limit, %
2
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective.
Fire potential
May burn but does not ignite readily.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Combustion products
When heated to decompose it emits acrid smoke and irritating fumes.
Health
3
 
Flammability
2
 
 
Reactivity
0
 

Health.
Poison_Class
5
Exposure effects
Animals given large intravenous doses develop CNS depression and convulsions. In a frog embryo teratogenesis assay, microencephaly and defects in eye and gut formation were most commonly seen.
   Ingestion
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May be harmful if swallowed.
   Inhalation
May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. Causes chemical burns to the respiratory tract.
   Skin
Harmful if absorbed through the skin. Causes skin burns.
   Eyes
Causes eye burns.

First aid
 
   Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
   Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Transport.
UN number
2820
Response guide
Hazard class
8
Packing Group
III
 
USCG CHRIS Code
BRA
 
HS Code
2915 60 19
 
Std. Transport #
4931414
 
IMO Pollution Category
D
IMO Hazard code
S