Chlorodiisopropylphosphine

  • Bis(1-methylethyl)phosphinous chloride
  • Diisopropylphosphinyl chloride
  • Diisopropylphosphine chloride
  • Chlorobis(isopropyl)phosphine
Formula
C6H14ClP
Structure
Description
Liquid. With a stench.

Registry Numbers and Inventories.
CAS
40244-90-4
Beilstein/Gmelin
1918497

Properties.
Formula
C6H14ClP
Formula mass
152.60
Boiling point, °C
69
Density
0.95 g/cm3
Solubility in water
Insoluble
Refractive index
1.475 (20 C)

Hazards and Protection.
Storage
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.
Handling
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Stability
No data.
Incompatibilities
Strong oxidizing agents.
Decomposition
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.

Fire.
Flash Point,°C
3
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use foam, dry chemical, or carbon dioxide.

Health.
Exposure effects
   Ingestion
Causes gastrointestinal tract burns. May cause headache. May cause nausea and vomiting.
   Inhalation
Causes chemical burns to the respiratory tract.
   Skin
Causes skin burns.
   Eyes
Causes eye burns.

First aid
 
   Ingestion
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.