- Dimethylhydrosilyl chloride
- Dimethylsilyl chloride
- Silane, chlorodimethyl-
Clear, colorless liquid.
Registry Numbers and Inventories.
extremely flammable, irritant
R 11 34 37
S 16 23 26 36/37/39 45
Japan ENCS (MITI)
Melting point, °C
Boiling point, °C
Vapor pressure, mmHg
143 (20 C)
0.863 g/cm3 (20 C)
Solubility in water
1.38 (20 C)
Heat of vaporization
Hazards and Protection.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Stable under normal temperatures and pressures.
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, silicon oxide.
Upper exp. limit, %
Lower exp. limit, %
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Extremely flammable liquid. Containers may explode in the heat of a fire. Will be easily ignited by heat, sparks or flame. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. For fires involving chlorosilanes a aqueous film forming foam (AFFF) may be used. DO NOT USE dry chemicals, soda ash, or lime on chlorosilane fires as they may release large quantities of hydrogen gas which may explode.
Flammable/combustible material. May be ignited by heat, sparks or flames.
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Fire will produce irritating, corrosive and/or toxic gases.
NIOSH TWA: 5 mg/m3
The toxicological properties of this substance have not been fully investigated.
Vapors may cause dizziness or suffocation.
No information regarding skin irritation and other potential effects was found.
No information regarding eye irritation and other potential effects was found.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
I; II; III
2931 00 95
Std. Transport #