Copper 8-quinolate

  • Oxine-copper
  • Copper-8-hydroxyquinoline
  • 8-Quinolinol, copper(II) chelate
  • Copper-8-hydroxyquinoline
Formula
C18H12CuN2O2
Structure
Description
Yellow to green crystalline solid.
Uses
Fungicide. In wood preservatives.

Registry Numbers and Inventories.
CAS
10380-28-6
EC (EINECS/ELINCS)
233-841-9
RTECS
VC5250000
RTECS class
Agricultural Chemical and Pesticide; Tumorigen; Mutagen
Beilstein/Gmelin
NA
EPA OPP
24002
Swiss Giftliste 1
G-2345
Canada DSL/NDSL
NDSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C18H12CuN2O2
Formula mass
351.86
Decomposition point, °C
>270
Density
1.63 g/cm3 (20 C)
Solubility in water
Insoluble

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Protective gloves. Safety goggles.
Respirators
Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
Small spills/leaks
Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.
Stability
No data.
Incompatibilities
Strong oxidizing agents.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.

Health.
Exposure limit(s)
NIOSH REL*: TWA 1 mg/m3 OSHA PEL*: TWA 1 mg/m3 [*Note: REL and PEL also apply to other copper compounds (as Cu) except copper fume.] IDLH 100 mg/m3 (as Cu)
Poison_Class
5
Exposure effects
The toxological properties of this substance have not been fully investigated.
   Inhalation
Abdominal pain, diarrhea, labored breathing vomiting. May cause asthmatic reactions.

First aid
 
   Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
   Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
   Skin
Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.
   Eyes
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.

Transport.