Copper(II) chloride dihydrate

  • Cupric chloride dihydrate
Formula
CuCl2.2H2O
Structure
Description
green-blue orthorhombic crystals, hygroscopic

Registry Numbers and Inventories.
CAS
10125-13-0
EC (EINECS/ELINCS)
231-210-2
R 22 37/38 41
S 26 36/37/39
RTECS
GL7030000
RTECS class
Other
UN (DOT)
2802
Merck
13,2660
Beilstein/Gmelin
11032 (G)
EPA OPP
23701
Swiss Giftliste 1
G-1017
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed

Properties.
Formula
Cl2CuH4O2
Formula mass
170.48
Melting point, °C
100
Vapor density (air=1)
5.9
Density
2.39 g/cm3 (22.9 C)

Hazards and Protection.
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Handling
Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Moisture, heat, potassium, sodium, alkali metals.
Decomposition
Hydrogen chloride, irritating and toxic fumes and gases, chloride fumes.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Extinguishing media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Fire potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Hazards
Contact with metals may evolve flammable hydrogen gas.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
2
 
Flammability
0
 
 
Reactivity
0
 

Health.
Poison_Class
3
Exposure effects
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed. Individuals with Wilson's disease are unable to metabolize copper. Thus, copper accumulates in various tissues and may result in liver, kidney, and brain damage.
   Ingestion
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause hemorrhaging of the digestive tract. The toxicological properties of this substance have not been fully investigated.
   Inhalation
Causes respiratory tract irritation. May cause ulceration and perforation of the nasal septum if inhaled in excessive quantities. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
   Skin
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause irritation with burning pain, itching and redness.
   Eyes
Causes eye irritation. Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities. Contact with the eyes may cause corneal damage.

First aid
 
   Ingestion
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
   Skin
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
2802
Response guide
Hazard class
8
Packing Group
III