Cyclopropyl methyl ketone

  • 1-Cyclopropylethanone
  • Acetylcyclopropane
  • Methyl cyclopropyl ketone
Formula
C5H8O
Structure
Description
Clear colorless to slightly yellow liquid. Characteristic odor.

Registry Numbers and Inventories.
CAS
765-43-5
EC (EINECS/ELINCS)
212-146-4
EC Class
highly flammable
S 16 23 33
RTECS
KM5648000
RTECS class
Primary Irritant
UN (DOT)
1224
Beilstein/Gmelin
1633817
Beilstein Reference
4-07-00-00014
Austrailia AICS
Listed
New Zealand
Listed

Properties.
Formula
C5H8O
Formula mass
84.12
Melting point, °C
-68
Boiling point, °C
114
Decomposition point, °C
227 - 232
Vapor pressure, mmHg
31 (18 C)
Density
0.8985 g/cm3 (16 C)
Solubility in water
Very soluble
Surface tension
30.8 g/s2 (18 C)
Refractive index
0 .8945 (25 C)
Partition coefficient, pKow
0.21
Heat of vaporization
40.48 kJ/mol

Hazards and Protection.
Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.
Handling
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Disposal code
1
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, reducing agents, strong bases.
Decomposition
Carbon monoxide, carbon dioxide.

Fire.
Flash Point,°C
13
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide.
Fire potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure effects
The toxological properties of this substance have not been fully investigated.
   Ingestion
May cause irritation of the digestive tract. May be harmful if swallowed.
   Inhalation
May cause respiratory tract irritation. May be harmful if inhaled.
   Skin
May cause skin irritation. May be harmful if absorbed through the skin.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
Get medical aid. Wash mouth out with water.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
1224
Response guide
Hazard class
3
Packing Group
I; II; III
 
HS Code
2914 29 00