cis-3-Hexen-1-ol

  • 3-Hexen-1-ol, (3Z)-
  • cis-3-Hexenyl alcohol
  • Folic alcohol
  • Leaf alcohol
Formula
CH3CH2CH=CHCH2CH2OH
Structure
Description
Clear, colorless liquid.

Registry Numbers and Inventories.
CAS
928-96-1
EC (EINECS/ELINCS)
213-192-8
EC Class
flammable
S 23 24/25
RTECS
MP8400000
RTECS class
Other
UN (DOT)
1987
Merck
13,4719
Beilstein/Gmelin
6409217
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C6H12O
Formula mass
100.16
Melting point, °C
-60
Boiling point, °C
156
Critical temperature
337
Critical pressure
36.3
Density
0.846 g/cm3 (22 C)
Solubility in water
Slightly soluble
Refractive index
1.4380 (20 C)
Partition coefficient, pKow
1.48

Hazards and Protection.
Storage
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Refrigerator/flammables.
Handling
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.
Disposal code
1
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, strong acids.
Decomposition
Carbon monoxide, carbon dioxide.

Fire.
Flash Point,°C
55
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing media: Use carbon dioxide or dry chemical.
Fire potential
Flammable Liquid.
Hazards
Vapors can travel to a source of ignition and flash back.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
1
 
Flammability
2
 
 
Reactivity
0
 

Health.
Poison_Class
4 (Substances and products that must be considered harmful)
Exposure effects
   Ingestion
May cause irritation of the digestive tract.
   Inhalation
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
   Skin
May cause skin irritation.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
Get medical aid. Wash mouth out with water.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
1987
Response guide
Hazard class
3
Packing Group
I; II; III
 
20. Alcohols. Glycols
HS Code
2905 29 90