Dess-Martin periodinane

  • Triacetoxyperiodinane
  • 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Formula
C13H13IO8
Structure
Uses
Reagent for the selective oxidation of primary and secondary alcohols.

Registry Numbers and Inventories.
CAS
87413-09-0
R 5 8 36/37/38
S 7/8 26 36/37/39
UN (DOT)
1479
Merck
13,2950
Beilstein/Gmelin
4548207
New Zealand
Listed

Properties.
Formula
C13H13IO8
Formula mass
424.15
Melting point, °C
133

Hazards and Protection.
Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Keep away from combustible materials. Avoid contact unless wearing appropriate protective clothing. Stop leak if you can do it without risk. With clean shovel place material into clean, dry container and cover loosely; move containers from spill area.

Fire.
Fire fighting
Small Fires: Use water. Do not use dry chemicals or foams. carbon dioxide or Halon may provide limited control. Large Fires: Flood fire area with water from a distance.
Fire potential
These substances will accelerate burning when involved in a fire.
Hazards
May explode from heat or contamination. May react explosively with hydrocarbons (fuels). May ignite combustibles.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure effects
   Ingestion
Ingestion may cause severe injury, burns, or death.
   Inhalation
Vapors may cause injury, burns, death.
   Skin
Contact may result in injury, burns and death.
   Eyes
See Skin.

First aid
 
   Ingestion
Seek medical assistance.
   Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
   Skin
Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush with running water for at least 20 minutes.
   Eyes
In case of contact with substance, immediately flush with running water for at least 20 minutes.

Transport.
UN number
1479
Response guide