- Ethyl bromomalonate
Clear colorless to slightly yellow liquid.
Registry Numbers and Inventories.
S 26 36/37/39 45
Boiling point, °C
Vapor pressure, mmHg
0.054 (25 C)
Vapor density (air=1)
1.426 g/cm3 (15 C)
Solubility in water
39.1 g/s2 (-166.7 C)
1.4521 (20 C)
Partition coefficient, pKow
Heat of vaporization
Hazards and Protection.
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Stable under normal temperatures and pressures.
Strong bases, strong oxidizing agents.
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Combustible material: may burn but does not ignite readily.
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
Fire may produce irritating, corrosive and/or toxic gases.
Effects may be delayed.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Causes skin irritation.
Causes eye irritation. Lachrymator. May cause chemical conjunctivitis.
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
I; II; III