Ethyl anthranilate

  • 2-Carboethoxyaniline
  • o-(Ethoxycarbonyl)aniline
  • Ethyl o-Aminobenzoate
  • Ethyl 2-Aminobenzoate
  • 2-(Ethoxycarbonyl)aniline
  • 2-Aminobenzoic acid ethyl ester
Formula
2-(NH2)C6H4COOC2H5
Structure
Description
Colorless liquid with a fruity odor.
Uses
Flavor additive in bakery products, gelatin & puddings, frozen milk desserts, flavored beverages, candy toppings, chewing gum.

Registry Numbers and Inventories.
CAS
87-25-2
EC (EINECS/ELINCS)
201-735-1
R 36/38
RTECS
DG2448000
RTECS class
Primary Irritant
Beilstein/Gmelin
878874
Beilstein Reference
4-14-00-01008
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed

Properties.
Formula
C9H11NO2
Formula mass
165.19
Melting point, °C
12 - 14
Boiling point, °C
268
Vapor pressure, mmHg
0.01 (25 C)
Vapor density (air=1)
5.7
Density
1.1219 g/cm3 (18 C)
Solubility in water
Insoluble
Viscosity
3.22 cp (55 C)
Refractive index
1.55719 (20 C)
pKa/pKb
11.82 (pKb)
Partition coefficient, pKow
2.57
Heat of vaporization
50.3 kJ/mol

Hazards and Protection.
Storage
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
Disposal code
5
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Oxidizing agents, reducing agents, acids, bases.
Decomposition
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Fire.
Flash Point,°C
127
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water fog, dry chemical, carbon dioxide or alcohol type foam.
Fire potential
This material is probably combustible.

Health.
Exposure effects
   Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
   Inhalation
May cause respiratory tract irritation.
   Skin
May cause skin irritation.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
   Inhalation
Remove from exposure to fresh air immediately.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
HS Code
2922 49 95