Ethyl iodoacetate

  • Ethyl 2-iodoacetate
  • Ethyl monoiodoacetate
  • Iodoacetic acid ethyl ester
  • Acetic acid, iodo-, ethyl ester
  • KSK
Formula
ICH2COOC2H5
Structure
Description
Clear liquid.

Registry Numbers and Inventories.
CAS
623-48-3
EC (EINECS/ELINCS)
210-796-3
EC Class
irritant
R 36/38
S 7/9 23.2
RTECS
AI3575000
RTECS class
Other
UN (DOT)
1708
Beilstein/Gmelin
741934
Beilstein Reference
4-02-00-00535
Swiss Giftliste 1
G-5464
Canada DSL/NDSL
NDSL
US TSCA
Listed
New Zealand
Listed
Korea ECL
Listed

Properties.
Formula
C4H7IO2
Formula mass
214.00
Boiling point, °C
179
Vapor pressure, mmHg
5.3 (20 C)
Vapor density (air=1)
7.4
Density
1.832 g/cm3 (4 C)
Solubility in water
Insoluble
Refractive index
1.50789 (12.7 C)

Hazards and Protection.
Storage
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator (approx 4 C).
Handling
Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Provide ventilation. Do not get water inside containers.
Disposal code
9
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Acids, bases, strong oxidizing agents.
Decomposition
Carbon monoxide, carbon dioxide, hydrogen iodide.

Fire.
Flash Point,°C
76
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Water Reactive. Combustible Liquid. Substance may react with water, and may release corrosive and/or toxic gases. Containers may explode when heated. Vapors are flammable above 83C (182F) in vessels of adequate size. Extinguishing media: Do NOT use water directly on fire. Do NOT get water inside containers. Use dry chemical or carbon dioxide.
Fire potential
Combustible material: may burn but does not ignite readily.
Hazards
When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Poison_Class
1
Exposure effects
   Ingestion
May be fatal if swallowed. May cause central nervous system effects.
   Inhalation
Causes respiratory tract irritation.
   Skin
Causes skin irritation.
   Eyes
Causes severe eye burns.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.

Transport.
UN number
1708
Response guide
Hazard class
6.1
Packing Group
II
 
HS Code
2915 90 80