Heptachlor epoxide

  • Epoxyheptachlor
  • 1,4,5,6,7,8,8-heptachloro-2,3-epoxy-3a,4,7,7a-tetrahydro-4,7-methanoindan
  • 4,7-Methanoindan, 1,4,5,6,7,8,8-heptachloro-2,3-epoxy-3a,4,7,7a-tetrahydro
  • 2,5-Methano-2H-Oxireno[a]indene, 2,3,4,5,6,7,7-heptachlor-1a,1b,5,5a,6,6a-hexahydro
  • Velsicol 53-CS-17
Formula
C10H5Cl7O
Structure
Uses
Not avail as commercial product in usa, & it is not normally present in commercial heptachlor heptachlor epoxide is formed from heptachlor in the environment.

Registry Numbers and Inventories.
CAS
1024-57-3
EC (EINECS/ELINCS)
213-831-0
EC Index Number
602-063-00-5
EC Class
Toxic; Carcinogenic Category 3; Danger of cumulative effects; Dangerous for the Environment
RTECS
PB9450000
RTECS class
Agricultural Chemical and Pesticide; Tumorigen; Mutagen
UN (DOT)
2761
Beilstein/Gmelin
90450
Beilstein Reference
5-17-01-00616
RCRA
D031
Austrailia AICS
Listed

Properties.
Formula
C10H5Cl7O
Formula mass
389.30
Melting point, °C
160-162
Boiling point, °C
425
Vapor pressure, mmHg
5E-7 (25 C)
Odor Threshold Odor threshold 0.02 ppm
Density
1.58 g/cm3
Solubility in water
0.350 ppm
Partition coefficient, pKow
5.40
Heat of vaporization
65.4 kJ/mol

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.
Respirators
Wear a NIOSH-approved half face respirator equipped with a combination filter cartridge, i.e. organic vapor/acid gas/HEPA (specific for organic vapors, HCl, acid gas, SO2 and a high efficiency particulate filter).
Small spills/leaks
If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Stability
No data.
Incompatibilities
May react with acids, bases, and oxidizing and reducing agents.

Fire.
Flash Point,°C
162
Fire fighting
To extinguish a fire involving this chemical you may use a dry chemical, carbon dioxide, foam or halon extinguisher; a water spray may also be used.
Fire potential
Non-Combustible
Combustion products
Hydrogen chloride fumes gas may form in fire.

Health.
Exposure limit(s)
0.05 mg/m3 TLV
Carcinogin
G-A3, I-2B, CP65
Exposure effects
CNS excitation, seizures, tremor, ataxia, agitation, nervousness, and amnesia may occur. Kelthane, perthane, methoxychlor, and hexachlorobenzene have little CNS toxicity; in extreme overdose CNS depression may occur. Organochlorine pesticides such as DDT pass through the placenta, with an average level in the newborn blood reaching around a third of that in maternal blood. They can also be found in breast milk. Excessive absorption of kepone (chlordecone) has depressed sperm counts and sperm motility in exposed workers.
   Ingestion
Nausea, vomiting, and diarrhea may follow ingestion.
   Inhalation
Aspiration of insecticide containing petroleum distillate may result in pneumonitis.
   Skin
Extensive contact results in dermal irritation.
   Eyes
See Inhalation.

First aid
 
   Ingestion
If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. MMEDIATELY transport the victim to a hospital.
   Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
   Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
   Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Transport.
UN number
2761
Response guide
Hazard class
6.1
Packing Group
I; II; III
 
USCG CHRIS Code
HPP