- 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate
- 2,2,2-Trifluoro-1-(trifluoromethyl)ethyl methacrylate
- 2-Propenoic acid, 2-methyl-, 2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester
Production of polymers.
Registry Numbers and Inventories.
R 11 36/37/38
S 16 26 28
Japan ENCS (MITI)
Boiling point, °C
Vapor density (air=1)
1.33 (20 C)
Hazards and Protection.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Wear appropriate protective gloves, clothing and goggles.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stable at room temperature in closed containers under normal storage and handling conditions.
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, fluoride fumes, fluorine.
Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, carbon dioxide, water spray or regular foam. Large Fires: Water spray, fog or regular foam. Do not use straight streams.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Fire will produce irritating, corrosive and/or toxic gases.
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation.
Causes skin irritation.
Causes eye irritation.
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice.
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
In case of contact with substance, immediately flush with running water for at least 20 minutes.