Linalool

  • Linalyl alcohol
  • 3,7-Dimethyl-1,6-octadien-3-ol
Formula
(CH3)2CCHCH2CH2C(C
Structure
Description
Odor similar to that of bergamot oil & french lavender.
Uses
In perfume instead of bergamot or french lavender oil since it has an odor similar to these oils.

Registry Numbers and Inventories.
CAS
78-70-6
EC (EINECS/ELINCS)
201-134-4
R 36/38
RTECS
RG5775000
RTECS class
Mutagen; Primary Irritant
Merck
13,5517
Beilstein/Gmelin
1721488
Beilstein Reference
0-01-00-00462
EPA OPP
128838
Swiss Giftliste 1
G-8701
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C10H18O
Formula mass
154.25
Boiling point, °C
199
Vapor pressure, mmHg
0.2 (25 C)
Vapor density (air=1)
5.3
Density
0.87 g/cm3 (20 C)
Solubility in water
1.6 g/L
Viscosity
4.4 MPA 25.00 C
Refractive index
1.46 (20 C)
Partition coefficient, pKow
2.97

Hazards and Protection.
Storage
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Oxidizing agents
Decomposition
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Fire.
Flash Point,°C
76
Autoignition, °C
235
Upper exp. limit, %
5.2
Lower exp. limit, %
0.9
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
Health
1
 
Flammability
2
 
 
Reactivity
0
 

Health.
Poison_Class
4
Exposure effects
Narcosis and ataxia occurred in poisoned animals.
   Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
   Inhalation
May cause respiratory tract irritation.
   Skin
Causes skin irritation.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
20. Alcohols. Glycols
HS Code
2905 22 10