Mercury(I) sulfate

  • Mercurous sulfate
  • Dimercury sulfate
Formula
Hg2SO4
Structure
Description
White to yellow crystalline powder.
Uses
For making electric batteries, with zinc sulfate in standard clark cell and with cadmium sulfate in std weston cell.

Registry Numbers and Inventories.
CAS
7783-36-0
EC (EINECS/ELINCS)
231-993-0
RTECS
OX0480000
RTECS class
Other
UN (DOT)
1628
Merck
12,5956
Beilstein/Gmelin
57694 (G)
RCRA
D009
Canada DSL/NDSL
DSL
Austrailia AICS
Listed
Korea ECL
Listed

Properties.
Formula
Hg2O4S
Formula mass
497.23
Melting point, °C
-38.9
Boiling point, °C
356.6
Vapor pressure, mmHg
0.0012
Density
7.121 g/cm3 (15 C)

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Stability
No data.
Incompatibilities
Incompatible with the following: Acetylene, ammonia, chlorine dioxide, azides, calcium (amalgam formation), sodium carbide, lithium, rubidium, copper.

Fire.
Fire fighting
SMALL FIRES: Dry chemical, carbon dioxide or water spray. LARGE FIRES: Water spray, fog or regular foam. Move containers from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Use water spray or fog; do not use straight streams. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
Fire potential
Non-Combustible
Hazards
Containers may explode when heated. Runoff may pollute waterways.
Combustion products
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health.
Exposure effects
The toxological properties of this substance have not been fully investigated.
   Inhalation
Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Effects of contact or inhalation may be delayed.
   Skin
Avoid any skin contact. See Inhalation.
   Eyes
See Inhalation.

First aid
 
   Ingestion
Seek medical assistance.
   Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
   Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Immediately flush with running water for at least 20 minutes.

Transport.
UN number
1628
Response guide
Hazard class
6.1