Methyl 3-(trimethylsilyloxy)crotonate

  • 2-Butenoic acid, 3-[(trimethylsilyl)oxy]-, methyl ester, (2E)-
Formula
C8H16O3Si
Structure
Description
Colorless liquid. Slight odor.

Registry Numbers and Inventories.
CAS
26767-00-0
Beilstein/Gmelin
2356944
Austrailia AICS
Listed
Korea ECL
Listed

Properties.
Formula
C8H16O3Si
Formula mass
188.29
Boiling point, °C
73 - 75 (9 torr)
Density
0.94 g/cm3
Solubility in water
Insoluble

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container. Refrigerator (approx 4 C). Store under nitrogen.
Handling
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use and store under nitrogen. Use only in a chemical fume hood.
Protection
Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Stability
Stable under normal shipping and handling conditions.
Incompatibilities
Strong oxidizing agents, strong acids, strong bases.
Decomposition
Carbon monoxide, carbon dioxide, silicon oxide, formaldehyde.

Fire.
Flash Point,°C
63
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Under fire conditions, material may decompose to form flammable and/or explosive mixtures in air. Extinguishing media: Use foam, dry chemical, or carbon dioxide.

Health.
Exposure effects
   Ingestion
May cause irritation of the digestive tract. May be harmful if swallowed.
   Inhalation
Causes respiratory tract irritation. May be harmful if inhaled.
   Skin
Causes skin irritation. May be harmful if absorbed through the skin.
   Eyes
Causes eye irritation.

First aid
 
   Ingestion
Get medical aid. Wash mouth out with water.
   Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.