Nicotine sulfate

  • 1-1-Methyl-2-(3-pyridyl)-pyrrolidine sulfate
  • (S)-3-(1-Methyl-2-pyrrolidinyl)-pyridine sulfate
  • 1,3-(1-Methyl-2-pyrrolidyl)-Pyridine sulfate
Formula
(C10H14N2)2.H2O4S
Structure
Description
A white solid.
Uses
Insecticide

Registry Numbers and Inventories.
CAS
65-30-5
EC (EINECS/ELINCS)
200-606-7
RTECS
QS9625000
RTECS class
Agricultural Chemical and Pesticide; Reproductive Effector
UN (DOT)
1658
Beilstein/Gmelin
6100611
Beilstein Reference
4-23-00-01000
RCRA
P075
EPA OPP
56703
Swiss Giftliste 1
G-2631
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
Japan ENCS (MITI)
Listed

Properties.
Formula
C10H14N2*H2O4S
Formula mass
420.58
Vapor density (air=1)
14.5
Odor Threshold Odor threshold Odorless solid
Density
1.15 g/cm3 (20 C)
Solubility in water
Soluble

Hazards and Protection.
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Oxidizing agents.
Decomposition
Irritating and toxic fumes and gases.

Fire.
Autoignition, °C
244
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Do NOT use straight streams of water. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire is out.
Fire potential
Moderate when exposed to heat or flame.
Combustion products
Toxic oxides of nitrogen are produced during combustion of this material.
Health
3
 
Flammability
0
 
 
Reactivity
0
 

Health.
Poison_Class
1
Exposure effects
Reproductive effects have been reported in animals. May cause lung damage.
   Ingestion
May be fatal if swallowed. May cause irritation of the digestive tract. May cause central nervous system stimulation.
   Inhalation
Harmful if inhaled. May cause respiratory tract irritation. May cause lung damage.
   Skin
May cause skin irritation. May be fatal if absorbed through the skin.
   Eyes
May cause eye irritation.

First aid
 
   Ingestion
Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Remove all contaminated clothing immediately.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
UN number
1658
Response guide
Hazard class
6.1
Packing Group
II
 
USCG CHRIS Code
NCS
 
Std. Transport #
4921451 4921452