Nitrourea

  • N-Nitrocarbamide
Formula
CH3N3O3
Structure
Description
A colorless to white crystalline powder solid.
Uses
Explosive.

Registry Numbers and Inventories.
CAS
556-89-8
EC (EINECS/ELINCS)
209-144-0
UN (DOT)
0147
Merck
12,6749
Beilstein/Gmelin
1756639
Beilstein Reference
4-03-00-00248
Canada DSL/NDSL
NDSL
US TSCA
Listed
Japan ENCS (MITI)
Listed

Properties.
Formula
CH3N3O3
Formula mass
105.05
Decomposition point, °C
158 - 159
Vapor pressure, mmHg
3.7 (25 C)
Solubility in water
Very soluble
pKa/pKb
3.69 (pKa)
Partition coefficient, pKow
-1.08

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respirators
Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
Small spills/leaks
Keep sparks, flames, and other sources of ignition away.
Stability
No data.
Incompatibilities
Sensitive to heat and impact, while the pure material is much more insensitive If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation.

Fire.
Fire fighting
Dangerously explosive. Do not fight fires in a cargo of explosives. Evacuate area and let burn.

Health.
Exposure effects
The toxicological properties of this material have not been investigated.

First aid
 
   Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
   Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
   Skin
Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.
   Eyes
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.

Transport.
UN number
0147
Std. Transport #
4901532