(O,1,1,1,2,3,3,3-{2}-H8)Propan-2-ol

  • 2-Propan-1,1,1,2,3,3,3-d7-ol-d
Formula
[2H]8C3O
Structure
Description
Clear, colorless liquid.

Registry Numbers and Inventories.
CAS
22739-76-0
EC (EINECS/ELINCS)
245-189-2
EC Class
highly flammable, irritant
R 11 36 67
S 7 16 24/25 26
UN (DOT)
1219
Beilstein/Gmelin
362239 (G)
New Zealand
Listed

Properties.
Formula
C3D8O
Formula mass
68.14
Melting point, °C
-89.5
Boiling point, °C
82
Vapor pressure, mmHg
324 (20 C)
Density
0.89 g/cm3
Solubility in water
Soluble

Hazards and Protection.
Storage
Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.
Handling
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Protection
Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators
A NIOSH/MSHA approved or European Standard EN 149 air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.
Disposal code
3
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Oxidizing agents, acetaldeyde, chlorine, ethylene oxide, acids and isocyanates, hydrogen + palladium, nitroform, oleum, phosgene, potassium t-butoxide, oxygen, trinitromethane, barium perchlorate, tetrafluoroborate, chromium trioxide, sodium dichromate + sulfuric acid, aluminum, and aluminum triisopropoxide.
Decomposition
Carbon monoxide, carbon dioxide.

Fire.
Flash Point,°C
12
Autoignition, °C
425
Upper exp. limit, %
12.7
Lower exp. limit, %
2
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode in the heat of a fire. This chemical poses an explosion hazard. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective.
Fire potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.

Health.
Exposure effects
Prolonged or repeated skin contact may cause defatting and dermatitis. May cause allergic skin reaction in some individuals.
   Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
   Inhalation
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Inhalation of vapor may cause respiratory tract irritation. May cause narcotic effects in high concentration.
   Skin
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May cause irritation with pain and stinging, especially if the skin is abraded.
   Eyes
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
   Skin
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
UN number
1219
Response guide
Hazard class
3
Packing Group
II
 
HS Code
2845 90 10