Phenylhydrazine monohydrochloride

  • Phenylhydrazinium chloride
  • Hydrazine, phenyl-, monohydrochloride
Formula
C6H8N2.ClH
Structure
Description
White, odorless powder.

Registry Numbers and Inventories.
CAS
59-88-1
EC (EINECS/ELINCS)
200-444-7
EC Index Number
612-023-00-9
EC Class
Carcinogenic Category 2; Mutagenic Category 3; Toxic; Irritant; Sensitising; Dangerous for the Environment
R 45 23/24/25 36/38 43 48/23/24/25 50 68
S 53 45 61
RTECS
MV9000000
RTECS class
Tumorigen; Drug; Mutagen; Reproductive Effector
UN (DOT)
2811
Merck
12,7447
Beilstein/Gmelin
3594958
Beilstein Reference
3-15-00-00067
Swiss Giftliste 1
G-5669
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C6H9ClN2
Formula mass
144.61
Melting point, °C
243 - 246
Solubility in water
50 g/L

Hazards and Protection.
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from light. Store under an inert atmosphere.
Handling
Wash thoroughly after handling. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from light. Handle under an inert atmosphere. Store protected from air. Use only in a chemical fume hood.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Place under an inert atmosphere.
Disposal code
9
Stability
Stable under normal temperatures and pressures. May violently decompose at temperatures above 190 C.
Incompatibilities
Air, strong oxidizing agents, lead dioxide, common metals (expect aluminum), bases.
Decomposition
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Extinguishing media: Use extinguishing media most appropriate for the surrounding fire. In case of fire, use carbon dioxide, dry chemical, or water fog.
Fire potential
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Hazards
Toxic and irritating hydrogen chloride and oxides of nitrogen may be produced in fire. May be corrosive to metals.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
2
 
Flammability
0
 
 
Reactivity
0
 

Health.
Poison_Class
3
Exposure effects
Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact may cause conjunctivitis. May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. May cause fetal effects. May cause cancer according to animal studies. Laboratory experiments have resulted in mutagenic effects. Chronic inhalation may cause liver damage.
   Ingestion
Harmful if swallowed. May cause liver and kidney damage. Causes gastrointestinal tract irritation. May cause systemic effects by ingestion: blood hemolysis with or without anemia, methemoglobinemia-carboxyhemoglobinemia, and pulmonary changes. May cause central nervous system stimulation.
   Inhalation
Harmful if inhaled. Causes respiratory tract irritation. May cause effects similar to those described for ingestion. Acute exposure to low concentrations of hydrazines may cause and produce bronchial mucous destruction, pulmonary edema, cyanosis and possible death.
   Skin
Causes skin irritation. Harmful if absorbed through the skin. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause eczematous dermatitis with swelling and vesiculation.
   Eyes
Causes eye irritation.

First aid
 
   Ingestion
Induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
   Skin
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
   Eyes
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Transport.
UN number
2811
Response guide
Hazard class
6.1
Packing Group
I; II; III
 
USCG CHRIS Code
PHH
 
HS Code
2928 00 90