Pine oil

  • Yarmor
  • Terpineols
  • Oils, pine
Formula
Mixture
Description
A clear colorless to light amber colored liquid. Primarily comprised of terpene alcohols.
Uses
Insecticide, Microbiocide

Registry Numbers and Inventories.
CAS
8002-09-3
RTECS
TK5100000
RTECS class
Agricultural Chemical and Pesticide; Human Data; Primary Irritant
UN (DOT)
1272
Beilstein/Gmelin
NA
EPA OPP
67205
Swiss Giftliste 1
G-2112
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Korea ECL
Listed

Properties.
Melting point, °C
0-10
Boiling point, °C
195
Vapor density (air=1)
5.3
Density
0.95 g/cm3 (20 C)
Solubility in water
20 mg/L

Hazards and Protection.
Storage
Maintain in a cool, dry location in a sealed container.
Handling
Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.
Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Flammable and/or toxic gases are generated by combination with with alkali metals, nitrides, and strong reducing agents Reacts with oxoacids and carboxylic acids to form esters plus water Incompatible with oxidizing agents.
Decomposition
Carbon dioxide and carbon monoxide, various hydrocarbons.

Fire.
Flash Point,°C
65
Fire fighting
Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide.
Fire potential
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Hazards
Forms heavy black smoke and soot.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
2
 
Flammability
2
 
 
Reactivity
0
 

Health.
Poison_Class
4
Exposure effects
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness).
   Ingestion
Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury.
   Inhalation
Vapors may cause dizziness or suffocation. May cause irritation or burns.
   Skin
May cause mild skin irritation. Symptoms may include redness and burning of skin.
   Eyes
Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes.

First aid
 
   Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
   Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.
   Skin
Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with running water for at least 20 minutes
   Eyes
Flush with running water for at least 20 minutes.

Transport.
UN number
1272
Response guide
Hazard class
3
Packing Group
III
 
USCG CHRIS Code
OPI
 
34 Esters (33 Misc. hydrocarbon mixtures)
IMO Pollution Category
C
IMO Hazard code
P