- 4-Methylbenzoic acid
- p-Methylbenzoic acid
- p-Tolylcarboxylic acid
- p-Toluylic acid
- Crithminic acid
White powder. Sublimes.
Registry Numbers and Inventories.
R 22 36/37/38
S 26 36/37/39
Swiss Giftliste 1
Japan ENCS (MITI)
Melting point, °C
179 - 180
Boiling point, °C
Vapor pressure, mmHg
0.0025 (25 C)
1.06 g/cm3 (20 C)
Solubility in water
1.5086 (20 C)
Partition coefficient, pKow
Heat of vaporization
Hazards and Protection.
Store in a cool, dry place. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not ingest or inhale.
Eyes: Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stable under normal temperatures and pressures.
Strong oxidizing agents, strong bases.
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Upper exp. limit, %
Lower exp. limit, %
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
This material is probably combustible.
Prolonged or repeated skin contact may cause dermatitis.
May cause irritation of the digestive tract.
May cause respiratory tract irritation.
May cause skin irritation.
May cause eye irritation.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
4. Organic acids
2916 39 00