Salicylanilide

  • 2-(N-Phenylcarboxamido)phenol
  • 2-Hydroxy-N-phenylbenzamide
  • Salicylic acid anilide
  • Aseptolan
  • Salicylanilid
  • Shirlan
Formula
2-(OH)C6H4CONHC6H5
Structure
Description
odorless slightly brown solid
Uses
Antimildew, fungicide.

Registry Numbers and Inventories.
CAS
87-17-2
EC (EINECS/ELINCS)
201-727-8
EC Class
irritant
R 37/38
RTECS
VN7850000
RTECS class
Drug
Merck
12,8482
Beilstein/Gmelin
1108135
Beilstein Reference
4-12-00-00906
EPA OPP
77407
Swiss Giftliste 1
G-2506
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C13H11NO2
Formula mass
213.24
Boiling point, °C
294
Vapor pressure, mmHg
0.001 (25 C)
Density
1.33 g/cm3
Solubility in water
Insoluble
pKa/pKb
7.11 (pKa)
Partition coefficient, pKow
3.27
Heat of vaporization
55.5 kJ/mol
Heat of combustion
-6380 kJ/mol

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Use only in a well ventilated area. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Protection
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Vacuum or sweep up material and place into a suitable disposal container.
Disposal code
3
Stability
Stable under normal temperatures and pressures.
Incompatibilities
Strong oxidizing agents, strong bases, strong acids.
Decomposition
Nitrogen oxides, carbon monoxide, carbon dioxide.

Fire.
Flash Point,°C
132
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Health.
Poison_Class
4
Exposure effects
   Ingestion
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
   Inhalation
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
   Skin
Causes skin irritation.
   Eyes
Causes eye irritation.

First aid
 
   Ingestion
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
   Inhalation
Remove from exposure to fresh air immediately. Get medical aid.
   Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
   Eyes
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Transport.
HS Code
2924 29 95