Siduron

  • Dupont 1318
  • Dupont herbicide 1,318
  • n-(2-Methylcyclohexyl)-N'-phenylurea
  • 1-(2-Methylcyclohexyl)-3-phenylurea
  • n-Phenyl-N'-(2-methylcyclohexyl)urea
  • Tupersan
Formula
C14H20N2O
Structure
Description
White crystals. Odorless.
Uses
Herbicide.

Registry Numbers and Inventories.
CAS
1982-49-6
EC (EINECS/ELINCS)
217-844-2
RTECS
YT7350000
RTECS class
Agricultural Chemical and Pesticide; Mutagen
Merck
12,8631
Beilstein/Gmelin
2725940
Beilstein Reference
1-12-00-00232
EPA OPP
35509
Swiss Giftliste 1
G-6614
Austrailia AICS
Listed
Japan ENCS (MITI)
Listed

Properties.
Formula
C14H20N2O
Formula mass
232.33
Melting point, °C
130
Boiling point, °C
409
Density
1.08 g/cm3 (25 C)
Solubility in water
soluble
Partition coefficient, pKow
3.09

Hazards and Protection.
Storage
Store in a dry place.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respirators
Use NIOSH/MSHA approved respirator appropriate for exposure of concern.
Small spills/leaks
Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.
Stability
It is stable up to its MP and in water at neutral ph, but is slowly decomp in acid and alkaline media.
Incompatibilities
Strong oxidizing agents.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.
Fire potential
Nonflammable

Health.
Poison_Class
4
Exposure effects
   Ingestion
Nausea, vomiting, and diarrhea may be noted following ingestion.
   Skin
Cyanosis unresponsive to oxygen therapy may be noted in patients with methemoglobinemia due to absorption of excessive amounts of these agents.

First aid
 
   Ingestion
Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
   Inhalation
If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
   Skin
Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.
   Eyes
Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Transport.