- Lithium, (1-methylpropyl)-
Clear light yellow to yellow orange solid/liquid mixture.
Registry Numbers and Inventories.
R 11 15 34
S 26 36/37/39 43 45
Swiss Giftliste 1
Japan ENCS (MITI)
Hazards and Protection.
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep container closed to prevent drying out. Keep under a nitrogen blanket. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Keep away from organic halogens. Refrigerator/flammables. Keep containers tightly closed.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Use only in a chemical fume hood. Store and handle protected from air. Do not use if the material has evaporated to dryness. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite.
Stable under normal temperatures and pressures.
Acetonitrile + SO2, bromine pentafluoride, bromobenzene, carbon + lithium tetrachloroaluminate + sulfunyl chloride, carbon + sulfunyl chloride, chlorine tri or pentafluoride, diazomethane, diborane, ethylene, halocarbbons, halogens, hydrogen, mercury, metal chlorides + nitrogen, metal oxides and chalcogenides, metals, nitric acid, nitryly fluoride, non-metal oxides, platinum, pol(1,1-difluoroethylene-hexafluoropropylene) (viton), sodium carbonate, sulfur, sulfinyl chloride, sulfur dioxide, trifluoromethyl hypofluorite, halocarbons, halogens, iron(II) sulfide, manganese telluride, arsenic, beryllium, maleic anhydride, carbides, carbon dioxide, + water, chlorine, chromium, chromium trichloride, cobalt alloys, nickel alloys, nitrogen, organic matter, oxygen, phosphorus, rubber, silicates, sodium nitrite, tantalum (V) oxide, vanadium, zirconium tetrachloride, iodoform, nitrogen + metal chlorides, fluorine, ma
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, lithium hydroxide, butane, oxides of lithium.
DO NOT USE WATER, carbon dioxide OR FOAM ON MATERIAL ITSELF. It may react violently with water. Smothering may not be effect.
May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. May react vigorously or explosively on contact with water. May decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished.
Fire will produce irritating, corrosive and/or toxic gases.
Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.
Aspiration hazard. May cause central nervous system depression, kidney damage, and liver damage. Causes digestive tract burns with immediate pain, swelling of the throat, convulsions, and possible coma. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May cause ear ringing, blurred vision, thyroid abnormalities, photophobia, coma, and seizures. The characteristics of lithium toxicity include: tremors, nausea, slurred speech, sluggishness, vertigo, thirst, and increased urine output. Effects from continued exposure include apathy, anorexia, fatigue, lethargy, muscular weakness, and cardiac changes. Long term exposure may lead to hypothroidism, leukocytosis, edema, weight gain, memory impairment, seizures, kidney damage, shock, hypotennsion, cardiac arrhythmias, coma, and death. Lithium has been implicated in the development of aplastic anem
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Irritation may lead to chemical pneumonitis and pulmonary edema. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause effects similar to those described for ingestion.
Harmful if absorbed through the skin. Contact with liquid is corrosive and causes severe burns and ulceration.
Causes severe eye burns. May cause irreversible eye injury.
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.