Tolylfluanid

  • N-Dichlorofluoromethylthio-N',N'-dimethyl-N-p-tolylsulfamide
  • Methanesulfenamide, 1,1-dichloro-N-[(dimethylamino)sulfonyl]-1-fluoro-N-(4-methylphenyl)-
Formula
C10H13Cl2FN2O2S2
Structure
Description
Colorless solid
Uses
Pesticide.

Registry Numbers and Inventories.
CAS
731-27-1
EC (EINECS/ELINCS)
211-986-9
EC Index Number
613-116-00-7
23 36/37/38 43 48/20 50/53
24 26 37 38 45 60 61
RTECS
WO6560000
RTECS class
Agricultural Chemical and Pesticide
UN (DOT)
2761
Beilstein/Gmelin
2949607
Beilstein Reference
6-12
EPA OPP
309200
Swiss Giftliste 1
G-8712
Canada DSL/NDSL
DSL
Austrailia AICS
Listed
New Zealand
Listed
Korea ECL
Listed

Properties.
Formula
C10H13Cl2FN2O2S2
Formula mass
347.27
Melting point, °C
95 - 97
Boiling point, °C
366
Vapor pressure, mmHg
1.5E-5 (25 C)
Density
1.52 g/cm3 (25 C)
Solubility in water
Insoluble
Heat of vaporization
61.2 kJ/mol

Hazards and Protection.
Storage
Keep tightly closed.
Protection
Compatible chemical-resistant gloves. Chemical safety goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.
Incompatibilities
Strong oxidizing agents.
Decomposition
Thermal decomposition may produce carbon monoxide, carbon dioxide, and nitrogen oxides, Hydrogen chloride gas, Hydrogen fluoride, Hydrogen sulfide gas.

Fire.
Flash Point,°C
175
Fire fighting
Extinguish using Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Fire potential
Non-Combustible
Hazards
Emits toxic fumes under fire conditions.
Combustion products
Fire may produce irritating, corrosive and/or toxic gases.
Health
3
 
Flammability
-
 
 
Reactivity
-
 

Health.
Poison_Class
4
Exposure effects
Dangerous for the environment. Harmful in contact with skin and if swallowed. Toxic by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Harmful: danger
   Ingestion
Harmful if swallowed.
   Inhalation
Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Effects of contact or inhalation may be delayed.
   Skin
Avoid any skin contact. See Inhalation.
   Eyes
See Inhalation.

First aid
 
   Ingestion
Seek medical assistance.
   Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
   Skin
Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
   Eyes
Immediately flush with running water for at least 20 minutes.

Transport.
UN number
2761
Response guide
Hazard class
6.1
Packing Group
II