Triallylamine

  • N,N-di-2-Propenyl-2-propen-1-amine
  • Tri-2-propenylamine
Formula
C9H15N
Structure
Description
A colorless liquid with a fishlike odor.
Uses
Chemical intermediate for ion exchange resins & rubber.

Registry Numbers and Inventories.
CAS
102-70-5
EC (EINECS/ELINCS)
203-048-2
R 10 22 23/24 34
S 26 28 36/37/39 45
RTECS
XX5950000
RTECS class
Human Data; Primary Irritant
UN (DOT)
2610
Beilstein/Gmelin
1740881
Beilstein Reference
4-04-00-01061
Swiss Giftliste 1
G-2961
Canada DSL/NDSL
NDSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C9H15N
Formula mass
137.25
Boiling point, °C
150
Vapor pressure, mmHg
4 (25 C)
Odor Threshold Odor threshold 0.5 ppm.
Critical temperature
319
Critical pressure
24.3
Density
0.796 g/cm3
Solubility in water
2.5 g/L
Viscosity
2.7783x10-3 pa.s @ 200.00 K
Surface tension
3.5051x10-2 n/m @ 200.00 K
Refractive index
1.4486 (20 C)
pKa/pKb
5.69 (pKb)
Partition coefficient, pKow
2.59
Heat of vaporization
39.4 kJ/mol

Hazards and Protection.
Storage
In general, materials which are toxic as stored or which can decomp into toxic components should be stored in a cool, well-ventilated place, out of direct rays of the sun, away from areas of high fire hazard, and should be periodically inspected. Incompatible materials should be isolated from each other.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear positive pressure self-contained breathing apparatus (SCBA).
Small spills/leaks
Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. Use water spray to knock-down vapors.
Stability
No data.
Incompatibilities
Reacts violently with oxidizing agents Corrosive towards Al and Zn Incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides.
Decomposition
When heated to decomposition it emits toxic fumes of nitrogen oxides.

Fire.
Flash Point,°C
30
Autoignition, °C
204
Fire fighting
Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources.
Fire potential
Flammable/combustible material.
Hazards
May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Combustion products
Fire will produce irritating, corrosive and/or toxic gases.

Health.
Poison_Class
3
Exposure effects
   Ingestion
Nausea, vomiting and diarrhea are possible if ingested.
   Inhalation
Cough, tachypnea, and wheezing are common after inhalation.
   Skin
Redness, swelling and pain may occur.
   Eyes
Irritants may cause swelling, redness and pain at any site, especially at mucous membranes. The mouth, nose, and eyes are susceptible to these effects.

First aid
 
   Ingestion
DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.
   Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
   Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
   Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Transport.
UN number
2610
Response guide
Hazard class
3
Packing Group
III
 
7. Aliphatic amines
Std. Transport #
4909285