Trichloromethane-d

Formula
CDCl3
Structure
Description
Clear, colorless liquid. Sweet, fruity - ethereal odor.

Registry Numbers and Inventories.
CAS
865-49-6
EC (EINECS/ELINCS)
212-742-4
EC Class
harmful, irritant, carcinogenic
R 22 38 40 48/20/22
UN (DOT)
1888
Beilstein/Gmelin
141611 (G)
Canada DSL/NDSL
DSL
Austrailia AICS
Listed
New Zealand
Listed

Properties.
Formula
CCl3D
Formula mass
120.38
Melting point, °C
-64.1
Boiling point, °C
60.8
Vapor pressure, mmHg
1588 (20 C)
Density
1.5 g/cm3
Solubility in water
8.2 g/L (20 C)
Refractive index
1.4450 (20 C)

Hazards and Protection.
Storage
Store in a cool, dry place. Store in a tightly closed container.
Handling
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respirators
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Small spills/leaks
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Disposal code
2
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Incompatibilities
Strong oxidizing agents.
Decomposition
Hydrogen chloride, carbon monoxide, carbon dioxide, chlorine, phosgene gas.

Fire.
Fire fighting
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.

Health.
Exposure limit(s)
10 ppm TLV {48.9 mg/m3}
Carcinogin
G-A3, I-2B, N-2, CP65
Poison_Class
1* (Very strong toxins (carcinogenic, mutagenic, teratogenic))
Exposure effects
Possible cancer hazard based on tests with laboratory animals. Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. May cause liver and kidney damage. May cause fetal effects. Chronic exposure has been associated with an increased incidence of kidney, liver, rectal, bladder, colon, brain, and lymph node cancer. Toxicity may be increased by exposure to alcohol, steroids, and ketones.
   Ingestion
May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause cardiac disturbances.
   Inhalation
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause liver and kidney damage. May cause cardiac sensitization and possible failure.
   Skin
Causes irritation with burning pain, itching, and redness.
   Eyes
Vapors may cause eye irritation. Contact produces irritation, tearing, and burning pain. May cause conjunctivitis. Causes redness and pain.

First aid
 
   Ingestion
Get medical aid. Do NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice. Wash mouth out with water.
   Inhalation
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
   Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
   Eyes
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.

Transport.
UN number
1888
Response guide
HS Code
2845 90 10