Triglycol diacetate

  • 2,2'-(Ethylenedioxy)di(ethyl acetate)
  • 2,2’-[Ethane-1,2-diylbis(oxy)]bisethyl diacetate
Formula
C10H18O6
Structure
Description
Odorless clear colorless liquid.
Uses
Plasticizer.

Registry Numbers and Inventories.
CAS
111-21-7
EC (EINECS/ELINCS)
203-846-0
RTECS
YE4950000
RTECS class
Reproductive Effector; Primary Irritant
Beilstein/Gmelin
1789453
Beilstein Reference
4-02-00-00215
Swiss Giftliste 1
G-9235
Canada DSL/NDSL
NDSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C10H18O6
Formula mass
234.24
Melting point, °C
-60
Boiling point, °C
300
Vapor pressure, mmHg
0.003 (25 C)
Density
1.117 g/cm3 (20 C)
Solubility in water
Slightly soluble
Refractive index
1.4368 (20 C)
Partition coefficient, pKow
0.10
Heat of vaporization
52.5 kJ/mol

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respirators
Wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.
Small spills/leaks
If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Stability
Low degree of volatility.
Incompatibilities
Incompatible with acetic acid Incompatible with peroxides, strong oxidants, oxygen scavengers and heavy metal compounds.

Fire.
Flash Point,°C
125
Fire fighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used.
Fire potential
This chemical is combustible.
Health
0
 
Flammability
1
 
 
Reactivity
0
 

Health.
Poison_Class
-
Exposure effects
Abnormally low blood pressure or elevated blood pressure may occur as a result of glycol toxicity. Rapid breathing has been reported with ethylene glycol and glycol ether ingestions. CNS depression, seizures, coma, cerebral edema, and delayed neurologic sequelae may occur following most glycol exposures. CNS symptoms are common following exposures to most glycols. Exposures to glycols have resulted in teratogenicity, specifically craniofacial and neural tube closure defects and skeletal dysplasia in animal studies.
   Ingestion
Nausea and vomiting are frequent early findings.
   Inhalation
Tachypnea, respiratory irritation, and pulmonary edema have been reported following exposure to glycols.
   Eyes
Eye irritation may occur with any of the glycols.

First aid
 
   Ingestion
DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.
   Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
   Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
   Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Transport.