tert-Dodecanethiol

  • tert-Lauryl mercaptan
  • tert-Dodecyl mercapta
  • tert-Dodecyl thiol
  • Sulfole 120
  • t-DDM
Formula
C12H26S
Structure
Description
White to yellow liquid.
Uses
Used as a chemical intermediate.

Registry Numbers and Inventories.
CAS
25103-58-6
EC (EINECS/ELINCS)
246-619-1
EC Class
irritant, dangerous for the environment
R 36/38 51/53
RTECS
JR3150000
RTECS class
Primary Irritant
UN (DOT)
3336
Beilstein/Gmelin
1738382
Beilstein Reference
3-01-00-01794
Swiss Giftliste 1
G-8020
Canada DSL/NDSL
DSL
US TSCA
Listed
Austrailia AICS
Listed
New Zealand
Listed
Japan ENCS (MITI)
Listed
Korea ECL
Listed

Properties.
Formula
C12H26S
Formula mass
202.40
Melting point, °C
-7.5
Boiling point, °C
189 - 207
Density
0.855 g/cm3 (20 C)
Refractive index
1.464 (20 C)

Hazards and Protection.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
D2B
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Protection
Wear appropriate protective gloves, clothing and goggles.
Respirators
Wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.
Small spills/leaks
If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Disposal code
6
Stability
No data.
Incompatibilities
Incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents Incompatible with oxygen Incompatible with strong oxidizing agents Sensitive to heat.

Fire.
Flash Point,°C
96
Fire fighting
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.
Fire potential
This chemical is combustible.
Hazards
Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
Combustion products
Fire will produce irritating, corrosive and/or toxic gases.

Health.
Poison_Class
4
Exposure effects
   Ingestion
See inhalation.
   Inhalation
Symptoms of exposure to this compound include slight irritation of the skin and eyes, headache, nausea, unconsciousness, sedation, muscle weakness, pulmonary edema and chemical pneumonitis.
   Skin
See inhalation.
   Eyes
See inhalation

First aid
 
   Ingestion
DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.
   Inhalation
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
   Skin
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
   Eyes
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Transport.
UN number
3336
Response guide
Hazard class
3
Packing Group
I; II; III
 
USCG CHRIS Code
DDL
 
HS Code
2930 90 70
 
IMO Chemical Code
17
IMO Pollution Category
A
IMO Hazard code
S/P